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Structurally stabilized composites are promising for using phase change materials in high‐temperature thermal energy storage (TES). However, conventional skeleton materials, which typically comprise 30–50 wt% of the composite, mainly provide sensible heat storage and contribute minimally to overall energy density. This study introduces a new class of redox‐active oxide‐molten salt (ROMS) composites that overcome this limitation by combining sensible, latent, and thermochemical heat storage in a single particle. Specifically, porous, redox‐active Ca2AlMnO5+δ(CAM) complex oxide particles were demonstrated as a suitable support matrix, with the pores filled by eutectic NaCl/CaCl2salt. X‐ray diffraction confirms excellent phase compatibility between CAM and the salt. Scanning electron microscopy/energy dispersive X‐ray spectroscopy and nano X‐ray tomography show good salt infiltration and wettability within the CAM pores. Thermogravimetric analysis reveals that a 60 wt% CAM/40 wt% salt composite achieves an energy density of 267 kJ kg−1over a narrow 150 °C window, with ≈50 kJ kg−1from thermochemical storage. Additionally, the composite shows higher thermal conductivity than salt alone, enabling faster energy storage and release. ROMS composites thus represent a novel and efficient solution for high‐performance TES.more » « lessFree, publicly-accessible full text available September 19, 2026
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